Upconversion-powered photoelectrochemistry.

نویسندگان

  • Rony S Khnayzer
  • Jörg Blumhoff
  • Jordan A Harrington
  • Alexandre Haefele
  • Fan Deng
  • Felix N Castellano
چکیده

Upconversion photochemistry occurring between palladium(II) octaethylporphyrin (PdOEP, 1) and 9,10-diphenylanthracene (DPA, 2) in toluene successfully sensitizes nanostructured WO(3) photoanodes (E(g) = 2.7 eV) to sub-bandgap non-coherent green photons at low power density.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Protein film photoelectrochemistry of the water oxidation enzyme photosystem II.

Photosynthesis is responsible for the sunlight-powered conversion of carbon dioxide and water into chemical energy in the form of carbohydrates and the release of O2 as a by-product. Although many proteins are involved in photosynthesis, the fascinating machinery of Photosystem II (PSII) is at the heart of this process. This tutorial review describes an emerging technique named protein film pho...

متن کامل

First-Principles View on Photoelectrochemistry: Water-Splitting as Case Study

Photoelectrochemistry is truly an interdisciplinary field; a natural nexus between chemistry and physics. In short, photoelectrochemistry can be divided into three sub-processes, namely (i) the creation of electron-hole pairs by light absorption; (ii) separation/transport on the charge carriers and finally (iii) the water splitting reaction. The challenge is to understand all three processes on...

متن کامل

Electrochemiluminescence induced photoelectrochemistry for sensing of the DNA based on DNA-linked CdS NPs superstructure with intercalator molecules.

A novel detection protocol of DNA was developed using electrochemiluminescence (ECL) induced photoelectrochemistry (PEC) synthesis based on DNA-linked CdS NPs superstructure with methylene blue as the intercalator molecule.

متن کامل

Highly Efficient Photon Upconversion in Self-Assembled Light-Harvesting Molecular Systems

To meet the world's demands on the development of sunlight-powered renewable energy production, triplet-triplet annihilation-based photon upconversion (TTA-UC) has raised great expectations. However, an ideal highly efficient, low-power, and in-air TTA-UC has not been achieved. Here, we report a novel self-assembly approach to achieve this, which enabled highly efficient TTA-UC even in the pres...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 48 2  شماره 

صفحات  -

تاریخ انتشار 2012